experimental examination of sulfur dioxide dry removal from a mixture of gases by calcium oxide, calcium carbonate and dolomite

Authors

slavko đurić

saša brankov

petko stanojević

ranko božičković

abstract

this paper refers to an experiment of so2 absorption to the three different sorbents: calcium-oxide (cao), calcium-carbonate (caco3) and dolomite (camg(co3)2). in the reactor under the condition of oxidation atmosphere with the mass of sorbent (sample) of 100 g with fractional composition of 500-700µm, the gas temperature varied from 200°c and 400°c. the examinations indicated that the highest degree of sorbent utilization of 14 % was determined for dolomite (camg(co3)2) and the binding degree of so2  from 65-80% and the lowest for calcium oxide  of 4% and the binding degree of so2  from 34-60% at the reaction temperature of 200°c. when the reaction temperature is 400°c the degree of sorbent utilization is a bit lower. the achieved results indicate the injection capability of powdered sorbents camg(co3)2, caco3 and cao in the areas of lower temperatures as it is the convective part of the boiler or furnace flue of the thermo power plant.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Experimental Examination of Sulfur Dioxide Dry Removal from a Mixture of Gases by Calcium Oxide, Calcium Carbonate and Dolomite

This paper refers to an experiment of SO2 absorption to the three different sorbents: calcium-oxide (CaO), calcium-carbonate (CaCO3) and dolomite (CaMg(CO3)2). In the reactor under the condition of oxidation atmosphere with the mass of sorbent (sample) of 100 g with fractional composition of 500-700µm, the gas temperatur...

full text

Heterogeneous oxidation of sulfur dioxide on calcium carbonate

L. Li, Z. M. Chen, Y. H. Zhang, T. Zhu, J. L. Li, and J. Ding State Key Joint Laboratory of Environment Simulation and Pollution Control, College of Environmental Sciences, Peking University, Beijing 100871, China Received: 18 October 2005 – Accepted: 9 December 2005 – Published: 17 January 2006 Correspondence to: Y. H. Zhang ([email protected]) © 2006 Author(s). This work is licensed under a ...

full text

Synthesis of calcium carbide-derived carbon by mechanochemical reaction of calcium carbide with sulfur, iron sulfide and zinc oxide

In the present work, we report a novel design and preparation for the mechanochemical synthesis of calcium carbide-derived carbon (CaC2-CDC) at ambient temperature. Thermodynamic calculations confirmed the possibility of calcium carbide-derived carbon formation by the reaction of calcium carbide with sulfur, iron sulfide and zinc oxide at ambient temperature. The CDCs were synthesized by the ba...

full text

Kinetics and mechanism of heterogeneous oxidation of sulfur dioxide by ozone on surface of calcium carbonate

Sulfate particles play a key role in the air quality and the global climate, but the heterogeneous formation mechanism of sulfates on surfaces of atmospheric particles is not well established. Carbonates, which act as a reactive component in mineral dust due to their special chemical properties, may contribute significantly to the sulfate formation by heterogeneous processes. This paper present...

full text

An experimental investigation on drying kinetics of calcium carbonate

Calcium carbonate is a versatile mineral with diverse industrial applications. Drying is a necessary processing step in preparation of calcium carbonate product. Deep knowledge of drying kinetics is required in order to design an appropriate dryer. The main aim of the present study was to investigate the drying kinetics of calcium carbonate, experimentally. Thirteen empirical correlations with ...

full text

My Resources

Save resource for easier access later


Journal title:
iranian journal of chemistry and chemical engineering (ijcce)

Publisher: iranian institute of research and development in chemical industries (irdci)-acecr

ISSN 1021-9986

volume 31

issue 2 2012

Keywords

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023